globalchange  > 气候减缓与适应
DOI: 10.1029/2018JE005544
Scopus记录号: 2-s2.0-85050947514
论文题名:
Identification of Chlorobenzene in the Viking Gas Chromatograph-Mass Spectrometer Data Sets: Reanalysis of Viking Mission Data Consistent With Aromatic Organic Compounds on Mars
作者: Guzman M.; McKay C.P.; Quinn R.C.; Szopa C.; Davila A.F.; Navarro-González R.; Freissinet C.
刊名: Journal of Geophysical Research: Planets
ISSN: 21699097
出版年: 2018
卷: 123, 期:7
起始页码: 1674
结束页码: 1683
语种: 英语
英文关键词: astrobiology ; chlorobenzene ; Mars ; organics ; SAM GCMS ; Viking GCMS
英文摘要: Motivated by the recent detection of chlorobenzene by the Sample Analysis at Mars instrument suite on the Curiosity rover, and the identification of its carbon source as indigenous to the martian sample, we reexamined the original, microfilm preserved, Viking gas chromatograph-mass spectrometer data sets. We found evidence for the presence of chlorobenzene in Viking Lander 2 (VL-2) data at levels corresponding to 0.08–1.0 ppb (relative to sample mass), in runs when the sample was heated to 350°C and 500°C. Additionally, we found a correlation between the temperature dependence of the chlorobenzene signal and the dichloromethane signal originally identified by the Viking gas chromatograph-mass spectrometer team. We considered possible sources of carbon that may have produced the chlorobenzene signal, by reaction with perchlorate during pyrolysis, including organic carbon indigenous to the martian parent sample and instrument contamination. We conclude that the chlorobenzene signal measured by VL-2 originated from martian chlorine sources. We show how the carbon source could originate from the martian parent sample, though a carbon source contributed from instrument background cannot yet be ruled out. ©2018. American Geophysical Union. All Rights Reserved.
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/113609
Appears in Collections:气候减缓与适应

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作者单位: ULATMOS/IPSL, UVSQ Université Paris-Saclay, UPMC Paris 06, CNRS, Guyancourt, France; NASA Ames Research Center, Moffett Field, CA, United States; Institut Universitaire de France, Paris, France; Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México, Ciudad de México, Mexico

Recommended Citation:
Guzman M.,McKay C.P.,Quinn R.C.,et al. Identification of Chlorobenzene in the Viking Gas Chromatograph-Mass Spectrometer Data Sets: Reanalysis of Viking Mission Data Consistent With Aromatic Organic Compounds on Mars[J]. Journal of Geophysical Research: Planets,2018-01-01,123(7)
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