DOI: 10.1016/j.jcou.2018.11.009
Scopus记录号: 2-s2.0-85057500979
论文题名: An alternative route of CO 2 conversion: Pd/C-catalyzed oxazolidinone hydrogenation to HCOOH and secondary alkyl-(2-arylethyl)amines with one stone two bird strategy
作者: Li Y.-N. ; Liu X.-F. ; He L.-N.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2019
卷: 29 起始页码: 74
结束页码: 81
语种: 英语
英文关键词: Formic acid
; Indirect hydrogenation of CO 2
; Oxazolidinone
; Palladium
; Secondary alkyl-(2-arylethyl)amines
Scopus关键词: Amines
; Birds
; Carbon dioxide
; Catalysts
; Formic acid
; Hydrogenation
; Palladium
; Alternative routes
; Carbon source
; Catalytic system
; Energy related products
; Functionalized
; High pressure
; Indirect hydrogenations
; Oxazolidinones
; Palladium compounds
英文摘要: The oxazolidinone as one kind of annular CO 2 derivatives has been hydrogenated by a new catalytic system Pd/C-TMGPEG 150 Me (polyethylene glycol-functionalized 1,1,3,3-tetramethyl guanidine), affording two valuable products i.e. formic acid and the corresponding secondary alkyl-(2-arylethyl)amines in the high yields of 89% and 98%, respectively. This hydrogenation can be carried out smoothly under relatively mild conditions of 60 °C, 4 MPa of H 2 with a liquid/solid carbon source (oxazolidinone) instead of high pressure CO 2 . The notable results can be successfully obtained even at room temperature under atmospheric H 2 pressure. This one stone two bird strategy is applicable to series of 5-aryl-2-oxazolidinones and opens up a novel way of synthesizing linear secondary alkyl-(2-arylethyl)amines without the selectivity issues, and validates a potential alternative approach for indirect conversion of CO 2 to energy-related products formic acid, as oxazolidinones can be readily obtained from hydrogenation of CO 2 . © 2018 Elsevier Ltd. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/117328
Appears in Collections: 气候变化与战略
There are no files associated with this item.
Recommended Citation:
Li Y.-N.,Liu X.-F.,He L.-N.. An alternative route of CO 2 conversion: Pd/C-catalyzed oxazolidinone hydrogenation to HCOOH and secondary alkyl-(2-arylethyl)amines with one stone two bird strategy[J]. Journal of CO2 Utilization,2019-01-01,29