globalchange  > 气候减缓与适应
DOI: 10.1021/acs.energyfuels.8b03796
WOS记录号: WOS:000459836800098
论文题名:
In Situ Imaging Studies of Combustor Pressure Effects on Soot Oxidation
作者: Sediako, Anton D.1; Bennett, Anthony2; Roberts, William L.2; Thomson, Murray J.1
通讯作者: Thomson, Murray J.
刊名: ENERGY & FUELS
ISSN: 0887-0624
EISSN: 1520-5029
出版年: 2019
卷: 33, 期:2, 页码:1582-1589
语种: 英语
WOS关键词: DIFFUSION FLAMES ; LAMINAR ; NANOSTRUCTURE ; FIELD
WOS学科分类: Energy & Fuels ; Engineering, Chemical
WOS研究方向: Energy & Fuels ; Engineering
英文摘要:

Airborne soot is a product of incomplete combustion from engines and industrial processes. Unburnt soot is carcinogenic, a major contributor to climate change, and detrimental to combustor lifespan and efficiency. An understanding of how high-pressure combustion affects the oxidation properties of soot is crucial for the design of clean-burning, high-pressure engines and downstream soot filtration technologies. This paper presents the first real-time look at the oxidation of soot particles formed at high pressure and demonstrates that the oxidation pathway changes as combustor pressures increase. Soot particles were formed in an ethylene-fueled diffusion flame, with pressures ranging from 1 to 25 bar, and were subsequently sampled and oxidized inside an ETEM allowing for the nanoscale, real-time observation of oxidation pathways. The high-pressure generated soot grew larger in diameter, formed larger aggregates, and developed graphitic outer shells, protecting the reactive amorphous carbon core. The graphitic shell structure fundamentally changed the oxidation pathway of soot from diffusion driven internal oxidation at lower pressures to highly nonreactive surface oxidation reactions at high pressures. This work demonstrates that as combustor pressures increase to achieve higher thermodynamic efficiencies, highly resilient oxidation-resistant soot is produced.


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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/128994
Appears in Collections:气候减缓与适应

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作者单位: 1.Univ Toronto, Dept Mech & Ind Engn, 5 Kings Coll Rd, Toronto, ON M5S 3G8, Canada
2.King Abdullah Univ Sci & Technol, Al Kindi Bldg 5,Level 4, Thuwal 239556900, Saudi Arabia

Recommended Citation:
Sediako, Anton D.,Bennett, Anthony,Roberts, William L.,et al. In Situ Imaging Studies of Combustor Pressure Effects on Soot Oxidation[J]. ENERGY & FUELS,2019-01-01,33(2):1582-1589
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