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Short periods of intense rainfall may be associated with significant impacts on society, particularly urban flooding. Climate model projections have suggested an intensification of precipitation under scenarios of climate change. This is in accordance with the hypothesis that precipitation intensities will increase with temperature according to the thermodynamic Clausius–Clapyeron (CC) relation (a rate of ~6–7% °C⁻¹)—a warmer atmosphere being capable of holding more moisture. Consequently, CC scaling between temperature and extreme precipitation has been demonstrated in numerous studies and in different locations, with higher than CC scaling (so-called super CC scaling) observed for sub-daily extremes. Here we use a new dataset of UK hourly precipitation to identify seasonal scaling relationships between mean daily temperature and 99th percentile hourly precipitation intensities. Pooling the data for the whole UK indicates only slightly higher than CC scaling in spring and summer at higher temperatures, notably less than the 2xCC scaling observed in other regions. Both the highest hourly intensities and the highest scaling in the UK occur in summer and so for this season the dependency of the scaling relationship on large scale circulation conditions is examined using a set of air flow indices. A shear vorticity index (indicative of large-scale flow cyclonicity) is noted to have the greatest influence on the relationship, approaching 2xCC at higher temperatures when shear vorticity is negative (anticyclonic rotation). An examination of the occurrence of intense events indicates that these can occur under cyclonic and anticyclonic conditions but that in the south-east of England the latter conditions disproportionately favour their occurrence. These results suggest that changes in circulation regimes could modify the expected changes in precipitation intensities prescribed by CC scaling and arising as a consequence of future warming.