globalchange  > 全球变化的国际研究计划
DOI: 10.1021/acssuschemeng.9b01603
WOS记录号: WOS:000475838100037
论文题名:
To Integrate or Not to Integrate-Techno-Economic and Life Cycle Assessment of CO2 Capture and Conversion to Methyl Formate Using Methanol
作者: Jens, Christian M.1; Mueller, Leonard1; Leonhard, Kaei1; Bardow, Andre1,2
通讯作者: Jens, Christian M. ; Mueller, Leonard ; Leonhard, Kaei ; Bardow, Andre
刊名: ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN: 2168-0485
出版年: 2019
卷: 7, 期:14, 页码:12270-12280
语种: 英语
英文关键词: Methyl formate ; Integrated CO2 capture and utilization ; ICCU ; ICCC ; Rectisol ; CO2-based methanol synthesis
WOS关键词: IN-SITU HYDROGENATION ; CARBON-DIOXIDE ; FORMIC-ACID ; CATALYSIS ; PLATINUM ; SYSTEMS ; STORAGE ; AMINE ; POLYETHYLENEIMINE ; EQUILIBRIA
WOS学科分类: Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS研究方向: Chemistry ; Science & Technology - Other Topics ; Engineering
英文摘要:

Utilizing CO2 to produce value-added chemicals can save environmental and economic impacts. However, these savings are reduced by the cost of CO2 supply when CO2 has to be captured from dilute sources. To reduce the cost of CO2 supply, the combination of CO2 capture and utilization has been suggested in a single integrated CO2 capture and utilization (ICCU) process. Although integration is intuitively appealing, a rigorous assessment of the savings by integration is missing. In this work, we evaluate if integration indeed increases savings, by comparing a utilization process without integration to a novel ICCU process. In the novel ICCU process, methanol absorbs CO2 from raw natural gas, before the mixture of CO2 and methanol is hydrogenated to methyl formate. We show that the novel ICCU process saves up to 46% of the electricity demand, which results in savings of up to 8 and 7% in the cost and the greenhouse gas emissions of the utilities, respectively. However, these savings are only enabled when raw natural gas with 30 mol % CO2 is employed; with lower CO2 concentrations, integration can even increase the cost and emissions of CCU. From the obtained results, we derive an indicator to assess the savings potential of ICCU processes. Finally, life cycle assessment reveals that CO2-based methyl formate has the potential to reduce both the global warming impact and the depletion of fossil resources compared to methyl formate produced from fossil sources.


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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/143379
Appears in Collections:全球变化的国际研究计划

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作者单位: 1.Rhein Westfal TH Aachen, Lehrstuhl Tech Thermodynam, Schinkelstr 8, D-52062 Aachen, Germany
2.Forschungszentrum Julich, Inst Energy & Climate Res Energy Syst Engn IEK 10, Julich, Germany

Recommended Citation:
Jens, Christian M.,Mueller, Leonard,Leonhard, Kaei,et al. To Integrate or Not to Integrate-Techno-Economic and Life Cycle Assessment of CO2 Capture and Conversion to Methyl Formate Using Methanol[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019-01-01,7(14):12270-12280
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