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The Surface Water and Ocean Topography (SWOT) satellite mission will, for the first time, provide simultaneous, high-resolution measurements of water surface elevation and extent. Here we explore the applicability of SWOT's unique sampling to capture discharge frequency behavior throughout the Mississippi River Basin. Our findings suggest the mission may capture key variability in river discharge series. SWOT orbit specifications, US Geological Survey (USGS) discharge measurements, and potential uncertainty estimates are used to generate SWOT-like river discharges. Frequency distributions and specific quantiles derived from synthetic SWOT discharge series are compared to those derived from daily USGS discharge series. Based on the Kolmogorov-Smirnov test, SWOT temporal sampling has essentially no impact on derived frequency distributions. When including potential uncertainty, 78% of derived distributions are statistically identical. The combined effects of temporal sampling and discharge uncertainty mitigates the negative bias used for SWOT discharge uncertainty at larger discharge quantiles (i.e., >= 75% quantiles).