| DOI: | 10.2172/1170616
|
| 报告号: | DOE-RUN--0007049-1
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| 报告题名: | Integrated Geophysical Measurements for Bioremediation Monitoring: Combining Spectral Induced Polarization, Nuclear Magnetic Resonance and Magnetic Methods |
| 作者: | Keating, Kristina; Slater, Lee; Ntarlagiannis, Dimitris; Williams, Kenneth H.
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| 出版年: | 2015
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| 发表日期: | 2015-02-24
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| 总页数: | 5
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| 国家: | 美国
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| 语种: | 英语
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| 英文关键词: | NMR, SIP, Magnetic Susceptibility,
|
| 中文主题词: | 碳
; 重金属
; 沉积物
; 铁
; 生物化学过程
; 金属
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| 主题词: | CARBON
; HEAVY METALS
; SEDIMENTS
; IRON
; BIOGEOCHEMICAL PROCESSES
; METALS
|
| 英文摘要: | This documents contains the final report for the project "Integrated Geophysical Measurements for Bioremediation Monitoring: Combining Spectral Induced Polarization, Nuclear Magnetic Resonance and Magnetic Methods" (DE-SC0007049) Executive Summary: Our research aimed to develop borehole measurement techniques capable of monitoring subsurface processes, such as changes in pore geometry and iron/sulfur geochemistry, associated with remediation of heavy metals and radionuclides. Previous work has demonstrated that geophysical method spectral induced polarization (SIP) can be used to assess subsurface contaminant remediation; however, SIP signals can be generated from multiple sources limiting their interpretation value. Integrating multiple geophysical methods, such as nuclear magnetic resonance (NMR) and magnetic susceptibility (MS), with SIP, could reduce the ambiguity of interpretation that might result from a single method. Our research efforts entails combining measurements from these methods, each sensitive to different mineral forms and/or mineral-fluid interfaces, providing better constraints on changes in subsurface biogeochemical processes and pore geometries significantly improving our understanding of processes impacting contaminant remediation. The Rifle Integrated Field Research Challenge (IFRC) site was used as a test location for our measurements. The Rifle IFRC site is located at a former uranium ore-processing facility in Rifle, Colorado. Leachate from spent mill tailings has resulted in residual uranium contamination of both groundwater and sediments within the local aquifer. Studies at the site include an ongoing acetate amendment strategy, native microbial populations are stimulated by introduction of carbon intended to alter redox conditions and immobilize uranium. To test the geophysical methods in the field, NMR and MS logging measurements were collected before, during, and after acetate amendment. Next, laboratory NMR, MS, and SIP measurements were collected on columns of Rifle sediments during acetate amendment. The laboratory experiments were designed to simulate the field experiments; changes in geophysical signals were expected to correlate with changes in redox conditions and iron speciation. Field MS logging measurements revealed vertically stratified magnetic mineralization, likely the result of detrital magnetic fraction within the bulk alluvium. Little to no change was observed in the MS data suggesting negligible production of magnetic phases (e.g. magnetite, pyrrhotite) as a result of sulfidogenesis. Borehole NMR measurements contained high levels of noise contamination requiring significant signal processing, and analysis suggests that any changes may be difficult to differentiate from simultaneous changes in water content. Laboratory MS and NMR measurements remained relatively stable throughout the course of the acetate amendment experiment, consistent with field measurements. However, SIP measurements changed during the acetate amendment associated with the formation of iron-sulfide mineral phases; a finding that is consistent with chemical analysis of the solid phase materials in the columns. |
| URL: | http://www.osti.gov/scitech/servlets/purl/1170616
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| Citation statistics: |
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| 资源类型: | 研究报告
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| 标识符: | http://119.78.100.158/handle/2HF3EXSE/41946
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| Appears in Collections: | 过去全球变化的重建
影响、适应和脆弱性
科学计划与规划
气候变化与战略
全球变化的国际研究计划
气候减缓与适应
气候变化事实与影响
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| 1170616.pdf（246KB） | 研究报告 | -- | 开放获取 | | View
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| Recommended Citation: | |
Keating, Kristina,Slater, Lee,Ntarlagiannis, Dimitris,et al. Integrated Geophysical Measurements for Bioremediation Monitoring: Combining Spectral Induced Polarization, Nuclear Magnetic Resonance and Magnetic Methods. 2015-01-01.
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