DOI: 10.1016/j.jcou.2017.05.015
Scopus记录号: 2-s2.0-85020250998
论文题名: A structure-activity controllable synthesis of skeletal CuAlZn catalyst for hydrogenation of bicarbonate to formic acid in water
作者: Jiang N. ; Sun H. ; Ren D. ; Pang Q. ; Jin F. ; Huo Z.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2017
卷: 20 起始页码: 218
结束页码: 223
语种: 英语
英文关键词: Bicarbonate
; Carbon dioxide
; Formic acid
; Green synthesis
; Skeletal CuAlZn catalyst
Scopus关键词: Carbon
; Carbon dioxide
; Catalysts
; Copper alloys
; Formic acid
; Hydrogenation
; Musculoskeletal system
; Reusability
; Bicarbonate
; Controllable synthesis
; Cu alloy
; Eco-friendly
; Green synthesis
; Structure activity
; Synthetic methods
; Catalyst activity
英文摘要: In this paper, a structure-activity controllable synthesis of ternary skeletal CuAlZn catalyst for NaHCO3 hydrogenation to produce formic acid was first investigated. Several kinds of Cu alloy and/or the synthetic methods were considered and their catalytic activities for hydrogenation of NaHCO3 were discussed. The results found that skeletal CuAlZn-2.5 h catalyst exhibited great catalytic activity to afford the maximum value of 86.1% of formic acid with 6 MPa H2 at 200 °C for 4 h. Reusability showed skeletal CuAlZn-2.5 h could still keep high catalytic activity for at least three times repeat. The present study provides an efficient and eco-friendly method for formic acid synthesis through All rights reserved.the hydrogenation of NaHCO3 or/and CO2. © 2017 Elsevier Ltd.All rights reserved. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/52715
Appears in Collections: 影响、适应和脆弱性