DOI: 10.1016/j.jcou.2016.09.006
Scopus记录号: 2-s2.0-84990818427
论文题名: Carbon dioxide and water: An effective multiphase medium for selective hydrogenation of nitriles with a Pd/Al2O3 catalyst
作者: Bhosale A. ; Yoshida H. ; Fujita S.-I. ; Arai M.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2016
卷: 16 语种: 英语
英文关键词: Multiphase media
; Nitriles
; Selective hydrogenation
; Selectivity control
; Water
Scopus关键词: Carbon
; Carbon dioxide
; Catalysts
; Hydrogenation
; Water
; Multi-phase medium
; Multiphase media
; Multiphase reactions
; Nitriles
; Pd/Al2O3 catalyst
; Selective hydrogenation
; Selective production
; Selectivity control
; Cyanides
英文摘要: Graphical abstract: The desired product of primary amines can selectively be produced in hydrogenation of nitriles using a multiphase reaction medium including both CO2 and H2O. The effectiveness of a multiphase medium including CO2 and water was studied for the selective hydrogenation various nitriles of 2-phenylethyl cyanide (PEC), cinnamonitrile, n-hexanenitrile (HN) and 4-cyanobiphenyl with a conventional Pd/Al2O3 catalyst. Such a multiphase reaction medium was observed to have different impacts changing from one nitrile to another and the selective production of primary amine was achieved with PEC and HN but not with the other nitriles. Possible reasons for the substrate-dependent effects of CO2 and water were discussed. © 2016 Elsevier Ltd. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/52845
Appears in Collections: 影响、适应和脆弱性
There are no files associated with this item.
Recommended Citation:
Bhosale A.,Yoshida H.,Fujita S.-I.,et al. Carbon dioxide and water: An effective multiphase medium for selective hydrogenation of nitriles with a Pd/Al2O3 catalyst[J]. Journal of CO2 Utilization,2016-01-01,16